Browsing by Author "Mbuvi, H. M."

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Adsorption Kinetics and Isotherms of Methylene Blue by Geopolymers Derived from Common Clay and Rice Husk Ash
(Physical Chemistry, 2017-10-07) Maingi, Francis M.; Mbuvi, H. M.; Ng’ang’a, M. M.; Mwangi, H.
With the onset of industrialization mankind has witnessed various environmental issues in the society. Industrialization has not only brought development and prosperity but eventually disturbed the ecosystem. It is currently estimated that 1.1 billion people in the world lack access to enhanced clean water supplies. Consequently, pursuance of sustainable materials and technologies for wastewater remediation is critical. Use of adsorbents for wastewater treatment is preferable due to their simplicity and cheap materials involved. Geopolymers are synthesized hydrothermally using alumina and silica which possesses amorphous surface for use as adsorbents. There is adequate information and reports in literature that indicate clay contain alumina and silica. Similarly, findings have shown that rice husk ash contains substantial amounts of silica. This work reports synthesis of geopolymers GP-1, GP-2 and GP-3 prepared by using different SiO2/Al2O3 ratios and consequently equilibrium and kinetics behaviour of adsorption of methylene blue. The geopolymers were characterized using FT-IR, EDS, XRD and SEM. Geopolymer adsorbents were subjected to methylene blue batch sorption experiments thate indicated the adsorption of MB increased with increased Si/Al ratio in geopolymers. The adsorption isotherms were described by Langmuir, Freundlich, Temkin and Sips isotherms. Data for adsorption of MB onto geopolymers fitted best in Sips adsorption model. Kinetic studies showed that Pseudo -second order model were more suitable than the Pseudo- first order model in explaining the kinetics of adsorption.
Adsorption of Cadmium Ions on Geopolymers Derived from Ordinary Clay and Rice Husk Ash
(International Journal of Materials and Chemistry, 2018-10-07) Maingi, Francis M.; Mbuvi, H. M.; Ng’ang’a, M. M.; Mwangi, H.
The presence of heavy metals in water is of growing concern. One crucial global strain is the existing disparity in water distribution resulting into millions of people lacking access to safe clean water. This is exasperated by the looming climate change and increased pollution impendence posed by industrialization and population growth. Consequently, pursuance of sustainable materials and technologies for wastewater remediation is critical. Adoption of adsorbents for water treatment is desirable due to their simplicity and cheap materials involved. Geopolymers are prepared hydrothermally using alumina and silica gleaned from clay and rice husks waste materials respectively. These materials are locally attainable and environmentally benign. This work reports synthesis of geopolymers GP-1, GP-2 and GP-3 prepared using clays from three different regions. The XRD diffraction patterns obtained revealed the presence of quartz (SiO2), albite (NaAlSi3O8), vermiculite (Mg,Fe,Al)3((Al,Si)4O10)(OH)2.4H2O), microcline (KAlSi3O8), analcime (NaAlSi2O6•H2O) and natrite (Na2CO3) among other crystalline phases. The initial adsorption rates were found to increase as the Si/Al ratio of the geopolymers increased. The adsorption rates were found to fit into the second order kinetic model. This implies that Cd (II) ions adsorb on geopolymer adsorbents through chemisorption.
Aluminophosphates Derived from Tea Leaves and Pumpkin Seeds Ashes Adsorb Lead Ions from Contaminated Water
(Frontiers in Science, 2018-10-08) Maingi, Francis M.; Mbuvi, H. M.; Ng’ang’a, M. M.
One major global challenge is the existing disparity in water distribution resulting to millions of people lacking access to safe clean water. This will certainly be exacerbated by the impending climate change and increased pollution threats posed by industrialization and population growth. Therefore pursuing sustainable materials and technologies for water remediation is crucial. Adsorbents use for water treatment is preferable owing to its simplicity and cheap materials involved. Aluminophosphates molecular sieves have open-framework structures that possess a wide range of pore openings and large surface area for use as adsorbents that can be synthesized hydrothermally using alumina and phosphates. Literature reports indicate that accumulation of aluminum in tea leaves correlates positively with leaf age. The EDXRF analysis showed that tea leaves ash used contained 30.09% of Al2O3. Similarly, literature findings indicate that pumpkin seeds contain relatively large amounts of phosphorous with the pumpkin seed ash used containing 37.01% of P2O5. Consequently, aluminophosphate APA and APB were synthesized using tea leaves to pumpkin seeds ash ratios of 1:1 and 1:2 respectively. XRD characterization and lead ions batch sorption experiments were done. Turbidity column experiment was done. Data for adsorption of Pb (II) ions data on the adsorbents best fitted into the Langmuir isotherm model. Adsorption capacities obtained from the linearized graphs were 90.91 and 50.0 mg/g for APA and APB respectively. This shows that tea leaves and pumpkin waste can synthesize aluminophosphate adsorbents. Aluminophosphates have shown good potential of removing Pb (II) ions from wastewaters.
Thermodynamic, Kinetic and Equilibrium Studies of Pb (II) Ions Adsorption Using Ordinary Clay/Rice Husk Ash Based Geopolymers
(IOSR Journal of Applied Chemistry, 2018-08-08) Maingi, Francis M.; Ng’ang’a, M. M.; Mwangi, H.; Mbuvi, H. M.; Abdulhameed, Adamu
One key global challenge is the existing disparity in water distribution resulting to millions of people lacking access to safe clean water. It is currently assessed that 1.1 billion individuals on the planet lacks access to improved quality water supplies. This is aggravated by the looming climate change and increased pollution threats posed by industrialization and population growth. Use of adsorbents for water treatment is preferable due to simplicity of the technique and cheap materials involved. Geopolymers can be easily synthesized hydrothermally using alumina and silica and possess amorphous surface for use as adsorbents. Clay minerals have been reported to contain alumina and silica and previous research show that rice husk ash as well contain substantial amounts of silica. Geopolymers can be easily synthesized hydrothermally using alumina and silica and possess amorphous surface that is useful for adsorption. Hence this work reports information on adsorption of Pb (II) using geopolymers GP-1, GP-2 and GP-3 synthesized with SiO2/Al2O3 ratios of 4.16, 4.18 and 8.29 respectively. Adsorption of metal ions was found to increase from 70.54%± 0.43 to 90.23% ± 0.04 with increase in Si/Al ratio from 4.16 to 8.29 in geopolymers. Equilibrium studies unveiled that experimental data for adsorption of Pb (II) ions best fitted in modified Langmuir Freundlich model. The adsorption capacities of 27.0, 79.58 and 209.9mg/g were obtained for GP-1, GP-2 and GP-3 respectively. Adsorption thermodynamics showed the process corresponded on spontaneous physiosorption activated by increase in temperature. Kinetic study on adsorption of Pb (II) ions onto clay based geopolymers was a Pseudo second order. This information may facilitate the development of optimized procedures for wastewater treatment, thus providing an alternative solution to environmental menace caused by heavy metal pollutants.