Geochronological and spatial distribution of heavy metal contamination in sediment from lake Naivasha, Kenya

Abstract

Sediment cores hold large information on the history of human interactions with lakes and surrounding environments. Hence, this study investigated the geochronological and heavy metals characteristics of sediment from Lake Naivasha, Kenya. Geochronological characteristics were established from sediment cores, using 210Pb and 137Cs. On the other hand, heavy metals; Al, As, Cr, Cu, Fe, Mn, Ni, Pb, and Zn were analyzed using Inductively Coupled Plasma - Optical Emission Spectrometer (ICP – OES). Their probable sources were predicted using Pearson’s correlation and Principal Component Analysis (PCA) while heavy metal contamination levels were assessed using geoaccumulation Index (Igeo), Contamination Factor (CF) and Enrichment Factor (EF) pollution indices. Results showed that the cores were about 140 years old with an estimated average mass sedimentation rate of 0.32 g/cm2/yr. Vertical fluctuations of heavy metal contamination were observed along the sediment cores with high values recorded near the surface. Further, PCA and pollution indices showed that Al, Cr, Cu, Ni, and Pb were from natural sources while, Zn, Mn, Fe, and As, (in order of contamination levels), were both from natural and anthropogenic sources. Therefore, this study showed the geochronological trends of sedimentation and impacts of human activities on Lake Naivasha.